The RPI is skewed early in the season. With 300+ teams and so few games played, this means good teams that have played more 250+ RPI teams rather than 150-250 RPI teams, haven't played/beaten enough tough teams to weather the skewness. So some teams that have played more 150-250 RPI teams have a much higher RPI than they deserve.
The skewness is always there but it has a diminishing return as more games are played. Hope that made sense and helps.